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[Sidenote: LONG WAVES MOST ABSORBED.]
It has already been stated that a layer of water less than the twentieth of an inch in thickness suffices to stop and destroy all waves of radiant heat emanating from an obscure source. The longer waves of the obscure heat cannot get through water, and I find that all transparent compounds which contain _hydrogen_ are peculiarly hostile to the longer undulations. It is, I think, the presence of this element in the humours of the eye which prevents the extra red rays of the solar spectrum from reaching the retina. It is interesting to observe that while bisulphide of carbon, chloride of phosphorus, and other liquids which contain no hydrogen, permit a large portion of the rays emanating from an iron or copper ball, at a heat below redness, to pa.s.s through them with facility, the same thickness of substances equally transparent, but which contain hydrogen, such as ether, alcohol, water, or the vitreous humour of the eye of an ox, completely intercepts these obscure rays. The same is true of solid bodies; a very slight thickness of those which contain hydrogen offers an impa.s.sable barrier to all rays emanating from a non-luminous source.[A] But the heat thus intercepted is by no means lost; its _radiant form_ merely is destroyed. Its waves are s.h.i.+vered upon the particles of the body, but they impart warmth to it, while the heat which retains its radiant form contributes in no way to the warmth of the body through which it pa.s.ses.
[Sidenote: FINAL COLOUR OF ICE AND WATER BLUE.]
Water then absorbs all the extra red rays of the sun, and if the layer be thick enough it invades the red rays themselves. Thus the greater the distance the solar beams travel through pure water the more are they deprived of those components which lie at the red end of the spectrum.
The consequence is, that the light finally transmitted by the water, and which gives to it its colour, is _blue_.
[Sidenote: EXPERIMENT.]
I find the following mode of examining the colour of water both satisfactory and convenient:--A tin tube, fifteen feet long and three inches in diameter, has its two ends stopped securely by pieces of colourless plate gla.s.s. It is placed in a horizontal position, and pure water is poured into it through a small lateral pipe, until the liquid reaches half way up the gla.s.ses at the ends; the tube then holds a semi-cylinder of water and a semi-cylinder of air. A white plate, or a sheet of white paper, well illuminated, is then placed at a little distance from one end of the tube, and is looked at through the tube.
Two semicircular s.p.a.ces are then seen, one by the light which has pa.s.sed through the air, the other by the light which has pa.s.sed through the water; and their proximity furnishes a means of comparison, which is absolutely necessary in experiments of this kind. It is always found that, while the former semicircle remains white, the latter one is vividly coloured.[B]
When the beam from an electric lamp is sent through this tube, and a convex lens is placed at a suitable distance from its most distant end, a magnified image of the coloured and uncoloured semicircles may be projected upon a screen. Tested thus, I have sometimes found, after rain, the ordinary pipe-water of the Royal Inst.i.tution quite opaque; while, under other circ.u.mstances, I have found the water of a clear green. The pump-water of the Inst.i.tution thus examined exhibits a rich sherry colour, while distilled water is blue-green.
The blueness of the Grotto of Capri is due to the fact that the light which enters it has previously traversed a great depth of clear water.
According to Bunsen's account, the _laugs_, or cisterns of hot water, in Iceland must be extremely beautiful. The water contains silica in solution, which, as the walls of the cistern arose, was deposited upon them in fantastic incrustations. These, though white, when looked at through the water appear of a lovely blue, which deepens in tint as the vision plunges deeper into the liquid.
[Sidenote: ICE OPAQUE TO RADIANT HEAT.]
Ice is a crystal formed from this blue liquid, the colour of which it retains. Ice is the most opaque of transparent solids to radiant heat, as water is the most opaque of liquids. According to Melloni, a plate of ice one twenty-fifth of an inch thick, which permits the rays of light to pa.s.s without sensible absorption, cuts off 94 per cent. of the rays of heat issuing from a powerful oil lamp, 99-1/2 per cent. of the rays issuing from incandescent platinum, and the whole of the rays issuing from an obscure source. The above numbers indicate how large a portion of the rays emitted by our artificial sources of light is obscure.
When the rays of light pa.s.s through a sufficient thickness of ice the longer waves are, as in the case of water, more and more absorbed, and the final colour of the substance is therefore blue. But when the ice is filled with minute air-bubbles, though we should loosely call it _white_, it may exhibit, even in small pieces, a delicate blue tint.
This, I think, is due to the frequent interior reflection which takes place at the surfaces of the air-cells; so that the light which reaches the eye from the interior may, in consequence of its having been reflected hither and thither, really have pa.s.sed through a considerable thickness of ice. The same remark, as we have already seen, applies to the delicate colour of newly fallen snow.
FOOTNOTES:
[A] What is here stated regarding hydrogen is true of all the liquids and solids which have hitherto been examined,--but whether any exceptions occur, future experience must determine. It is only when in combination that it exhibits this impermeability to the obscure rays.
[B] In my own experiments I have never yet been able to obtain a pure blue, the nearest approach to it being a blue-green.
COLOURS OF THE SKY.
(7.)
[Sidenote: NEWTON'S HYPOTHESIS.]
In treating of the Colours of Thin Plates we found that a certain thickness was necessary to produce blue, while a greater thickness was necessary for red. With that wonderful power of generalization which belonged to him, Newton thus applies this apparently remote fact to the blue of the sky:--"The blue of the first order, though very faint and little, may possibly be the colour of some substances, and particularly the azure colour of the skies seems to be of this order. For all vapours, when they begin to condense and coalesce into small parcels, become first of that bigness whereby such an azure is reflected, before they can const.i.tute clouds of other colours. And so, this being the first colour which vapours begin to reflect, it ought to be the colour of the finest and most transparent skies, in which vapours are not arrived at that grossness requisite to reflect other colours, as we find it is by experience."
M. Clausius has written a most interesting paper, which he endeavours to show that the minute particles of water which are supposed by Newton to reflect the light, cannot be little globes entirely composed of water, but bladders or hollow spheres; the vapour must be in what is generally termed the _vesicular_ state. He was followed by M. Brucke, whose experiments prove that the suspended particles may be so small that the reasoning of M. Clausius may not apply to them.
But why need we a.s.sume the existence of such particles at all?--why not a.s.sume that the colour of the air is blue, and renders the light of the sun blue, after the fas.h.i.+on of a blue gla.s.s or a solution of the sulphate of copper? I have already referred to the great variation which the colour of the firmament undergoes in the Alps, and have remarked that this seems to indicate that the blue depends upon some variable const.i.tuent of the atmosphere. Further, we find that the blue light of the sky is _reflected_ light; and there must be something in the atmosphere capable of producing this reflection; but this thing, whatever it is, produces another effect which the blue gla.s.s or liquid is unable to produce. These _transmit_ blue light, whereas, when the solar beams have traversed a great length of air, as in the morning or the evening, they are yellow, or orange, or even blood-red, according to the state of the atmosphere:--the transmitted light and the reflected light of the atmosphere are then totally different in colour.
[Sidenote: GOETHE'S HYPOTHESIS.]
Goethe, in his celebrated 'Farbenlehre,' gives a theory of the colour of the sky, and has ill.u.s.trated it by a series of striking facts. He a.s.sumed two principles in the universe--Light and Darkness--and an intermediate stage of Turbidity. When the darkness is seen through a turbid medium on which the light falls, the medium appears blue; when the light itself is viewed through such a medium, it is yellow, or orange, or ruby-red. This he applies to the atmosphere, which sends us blue light, or red, according as the darkness of infinite s.p.a.ce, or the bright surface of the sun, is regarded through it.
As a theory of colours Goethe's work is of no value, but the facts which he has brought forward in ill.u.s.tration of the action of turbid media are in the highest degree interesting. He refers to the blueness of distant mountains, of smoke, of the lower part of the flame of a candle (which if looked at with a white surface behind it completely disappears), of soapy water, and of the precipitates of various resins in water. One of his anecdotes in connexion with this subject is extremely curious and instructive. The portrait of a very dignified theologian having suffered from dirt, it was given to a painter to be cleaned. The clergyman was drawn in a dress of black velvet, over which the painter, in the first place, pa.s.sed his sponge. To his astonishment the black velvet changed to the colour of blue plush, and completely altered the aspect of its wearer. Goethe was informed of the fact; the experiment was repeated in his presence, and he at once solved it by reference to his theory. The varnish of the picture when mixed with the water formed a turbid medium, and the black coat seen through it appeared blue; when the water evaporated the coat resumed its original aspect.
[Sidenote: SUSPENDED PARTICLES.]
With regard to the real explanation of these effects, it may be shown, that, if a beam of white light be sent through a liquid which contains extremely minute particles in a state of suspension, the short waves are more copiously reflected by such particles than the long ones; blue, for example, is more copiously reflected than red. This may be shown by various fine precipitates, but the best is that of Brucke. We know that mastic and various resins are soluble in alcohol, and are precipitated when the solution is poured into water: _Eau de Cologne_, for example, produces a white precipitate when poured into water. If however this precipitate be sufficiently diluted, it gives the liquid a bluish colour by reflected light. Even when the precipitate is very thick and gross, and floats upon the liquid like a kind of curd, its under portions often exhibit a fine blue. To obtain particles of a proper size, Brucke recommends 1 gramme of colourless mastic to be dissolved in 87 grammes of alcohol, and dropped into a beaker of water, which is kept in a state of agitation. In this way a blue resembling that of the firmament may be produced. It is best seen when a black cloth is placed behind the gla.s.s; but in certain positions this blue liquid appears yellow; and these are the positions when the _transmitted_ light reaches the eye. It is evident that this change of colour must necessarily exist; for the blue being partially withdrawn by more copious reflection, the transmitted light must partake more or less of the character of the complementary colour; though it does not follow that they should be exactly complementary to each other.
[Sidenote: THE SUN THROUGH LONDON SMOKE.]
When a long tube is filled with clear water, the colour of the liquid, as before stated, shows itself by transmitted light. The effect is very interesting when a solution of mastic is permitted to drop into such a tube, and the fine precipitate to diffuse itself in the water. The blue-green of the liquid is first neutralized, and a yellow colour shows itself; on adding more of the solution the colour pa.s.ses from yellow to orange, and from orange to blood-red. With a cell an inch and a half in width, containing water, into which the solution of mastic is suffered to drop, the same effect may be obtained. If the light of an electric lamp be caused to form a clear sunlike disk upon a white screen, the gradual change of this light by augmented precipitation into deep glowing red, resembling the colour of the sun when seen through fine London smoke, is exceedingly striking. Indeed the smoke acts, in some measure, the part of our finely-suspended matter.
[Sidenote: MORNING AND EVENING RED.]
By such means it is possible to imitate the phenomena of the firmament; we can produce its pure blue, and cause it to vary as in nature. The milkiness which steals over the heavens, and enables us to distinguish one cloudless day from another, can be produced with the greatest ease.
The yellow, orange, and red light of the morning and evening can also be obtained: indeed the effects are so strikingly alike as to suggest a common origin--that the colours of the sky are due to minute particles diffused through the atmosphere. These particles are doubtless the condensed vapour of water, and its variation in quality and amount enables us to understand the variability of the firmamental blue, and of the morning and the evening red. Professor Forbes, moreover, has made the interesting observation that the steam of a locomotive, at a certain stage of its condensation, is blue or red according as it is viewed by reflected or transmitted light.
These considerations enable us to account for a number of facts of common occurrence. Thin milk, when poured upon a black surface, appears bluish. The milk is colourless; that is, its blueness is not due to _absorption_, but to a _separation_ of the light by the particles suspended in the liquid. The juices of various plants owe their blueness to the same cause; but perhaps the most curious ill.u.s.tration is that presented by a blue eye. Here we have no true colouring matter, no proper absorption; but we look through a muddy medium at the black choroid coat within the eye, and the medium appears blue.[A]
[Sidenote: COLOUR OF SWISS LAKES.]
Is it not probable that this action of finely-divided matter may have some influence on the colour of some of the Swiss lakes--as that of Geneva for example? This lake is simply an expansion of the river Rhone, which rushes from the end of the Rhone glacier, as the Arveiron does from the end of the Mer de Glace. Numerous other streams join the Rhone right and left during its downward course; and these feeders, being almost wholly derived from glaciers, join the Rhone charged with the finer matter which these in their motion have ground from the rocks over which they have pa.s.sed. But the glaciers must grind the ma.s.s beneath them to particles of all sizes, and I cannot help thinking that the finest of them must remain suspended in the lake throughout its entire length. Faraday has shown that a precipitate of gold may require months to sink to the bottom of a bottle not more than five inches high, and in all probability it would require _ages_ of calm subsidence to bring _all_ the particles which the Lake of Geneva contains to its bottom. It seems certainly worthy of examination whether such particles suspended in the water contribute to the production of that magnificent blue which has excited the admiration of all who have seen it under favourable circ.u.mstances.
FOOTNOTES:
[A] Helmholtz, 'Das Sehen des Menschen.'
THE MORAINES.
(8.)
The surface of the glacier does not long retain the s.h.i.+ning whiteness of the snow from which it is derived. It is flanked by mountains which are washed by rain, dislocated by frost, riven by lightning, traversed by avalanches, and swept by storms. The lighter debris is scattered by the winds far and wide over the glacier, sullying the purity of its surface.
Loose s.h.i.+ngle rattles at intervals down the sides of the mountains, and falls upon the ice where it touches the rocks. Large rocks are continually let loose, which come jumping from ledge to ledge, the cohesion of some being proof against the shocks which they experience; while others, when they hit the rocks, burst like bomb-sh.e.l.ls, and shower their fragments upon the ice.
[Sidenote: LATERAL MORAINES.]
Thus the glacier is incessantly loaded along its borders with the ruins of the mountains which limit it; and it is evident that the quant.i.ty of rock and rubbish thus cast upon the glacier depends upon the character of the adjacent mountains. Where the summits are bare and friable, we may expect copious showers; where they are resistant, and particularly where they are protected by a covering of ice and snow, the quant.i.ty will be small. As the glacier moves downward, it carries with it the load deposited upon it. Long ridges of debris thus flank the glacier, and these ridges are called _lateral moraines_. Where two tributary glaciers join to form a trunk-glacier, their adjacent lateral moraines are laid side by side at the place of confluence, thus const.i.tuting a ridge which runs along the middle of the trunk-glacier, and which is called a _medial moraine_. The rocks and debris carried down by the glacier are finally deposited at its lower extremity, forming there a _terminal moraine_.
[Sidenote: MEDIAL AND TERMINAL MORAINES.]
It need hardly be stated that the number of medial moraines is only limited by the number of branch glaciers. If a glacier have but two branches, it will have only one medial moraine; if it have three branches, it will have two medial moraines; if _n_ branches, it will have _n_-1 medial moraines. The number of medial moraines, in short, is always _one less_ than the number of branches. A glance at the annexed figure will reveal the manner in which the lateral moraines of the Mer de Glace unite to form medial ones. (See Fig. 19.)
[Ill.u.s.tration: MORAINES OF THE MER DE GLACE.