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powder (roasted peas coloured with reddle), and the marc of coffee; exhausted bark (from the tan yards), logwood dust, mahogany dust, &c. It has also been a.s.serted that the scorched livers of bullocks, horses, and dogs have been applied to the same purpose; but of this there is not sufficient evidence. The only way to avoid being thus cheated or poisoned is to buy the chicory whole, and to grind it at home.
[Ill.u.s.tration: Microscopic appearance of chicory root.]
Roasted chicory is highly absorbent of moisture, and should, therefore, be always kept in close vessels (bottles or canisters), the same as coffee.
If the lumps become tough or soft, or the powder cakes together, it is unfit for use; but in some cases it may be recovered, by exposing it on a plate in an oven until it again becomes perfectly dry or brittle.
_Tests._--1. Powdered chicory thrown on water turns it reddish-brown and rapidly sinks, leaving light impurities either floating or diffused through the liquid.--2. The cold decoction tested with tincture, or solution of iodine, gives a brown colour; if it turns purple, blue, or black, it indicates the presence of roasted peas, beans, rye, or some other like substance, containing starch.--3. Persulphate or perchloride of iron, added in the same way, should not materially affect the liquid; if it turns it bluish or blackish, it indicates the presence of roasted acorns, oak-bark tan, or some other substance containing tannin.--4. Water acidulated with vinegar, digested on the powder, should not be blackened, or even materially darkened, by tincture of galls or a solution of red prussiate of potash; the contrary shows the presence of ferruginous colouring matter.--5. The dry powder, when incinerated, should not leave more than 4-1/2 to 5% of ash, which should be of a greyish or fawn colour; the contrary indicates the presence of reddle, red clay, ochre, or the like.--6. To the above may be added attention to the odour, colour, and appearance, both to the naked eye and under the microscope; by the latter, adulteration may be easily detected. See COFFEE.
=CHIL'BLAIN.= _Syn._ PER'NIO, L. An inflammatory swelling, of a purple or lead colour, produced by the action of cold. Chilblains (PERNIO'NES) exclusively attack the extremities of the body, and are generally confined to the fingers, toes, and heels. The common symptoms are itching and irritation, more or less intense, often accompanied with shooting pains, and tenderness, and tumefaction of the parts. Children, especially those of a scrofulous habit, and elderly persons, are generally the most liable to chilblains. The common cause of chilblains is holding the hands or feet to the fire after exposure to cold. The sudden change of temperature partially destroys the vitality of the minute surfacial vessels, and thus prevents the proper flow of blood through the part. The best preventives of chilblains are woollen socks or stockings, good waterproof shoes, woollen gloves, exercise, and friction. These act by promoting the circulation of the blood in the extremities, and protecting them from vicissitudes of temperature. When chilblains have once formed, the best treatment is friction with stimulants, as spirits of wine and camphor, oil of turpentine, opodeldoc, dilute spirits, camphorated oil, hartshorn and oil, &c. Linnaeus recommends bathing the part with dilute muriatic acid, just strong enough to faintly p.r.i.c.k the skin. When the inflamed parts have ulcerated, they are commonly called KIBES. In this state they should be dressed with a little resin cerate or elemi ointment. If fungous granulations appear, they must be removed by touching them with nitrate of silver or blue vitriol. See CHAPS, &c.
REMEDIES FOR CHILBLAINS.--The following have been strongly recommended by different parties, and may all prove useful in their turns, as circ.u.mstances and convenience may suggest:--
1. Sulphate of copper, 1 oz.; rosemary water, 1 pint; dissolve.
2. Sal-ammoniac, 1 oz.; vinegar, 1/2 pint.
3. Sal-ammoniac, 1 oz.; rum, 1/2 pint; camphor, 1 dr. The affected part is wetted with the above night and morning, and when dry is touched with a little simple ointment, cold cream, or pomatum.
4. Soap liniment, 2 oz.; tincture of cantharides, 1 oz.; oil of cajeput, 2 dr.
5. Oil of turpentine, 2 oz.; camphor, 3 dr.; oil of cajeput, 1 dr. The application of the last two is accompanied by gentle friction.
6. (Dr GRAVES' PREVENTIVE.) Sulphate of copper, 20 gr.; water, 1 oz. As the first three.
7. (LEJEUNE'S BALSAM.) See CHILBLAIN BALSAM.
8. (LINNaeUS' REMEDY.) Hydrochloric acid, 1 oz.; water, 11 oz. As No. 3.
9. (MORTON'S LINIMENT.) Calomel and camphor, of each 1 dr.; spermaceti ointment, 4 dr.; oil of turpentine and cocoa-nut oil, of each 2 dr. As No.
5.
10. (WAHLER'S OINTMENT.) Black oxide of iron, bole, and oil of turpentine, of each 1 dr.; resin cerate, 1 oz. For broken chilblains. We have found a mixture of equal parts of calamine cerate and resin cerate answer quite as well. See CERATE, OINTMENT.
11. (RUSSIAN REMEDY.) The rind of perfectly ripe cuc.u.mbers dried, with the soft parts attached. For use they are placed with the inner side, previously soaked in warm water, over the soft parts. (Med. Zeitung.)
12. (RHEIN.) Dissolve 1 _oz._ of tannin in a pint of water, and 74 grains of iodine in 1-3/4 _oz._ of spirit of wine; the solutions are then mixed, and enough water added to make the whole up to 2-1/2 pints. In applying it, which is best done at bedtime, the mixture is gently warmed over a slow fire; the affected part is dipped into it while still cold, and retained in it till the liquid, on being stirred, feels uncomfortably hot.
The vessel is then withdrawn from the fire, and the affected part dried over it. The vessel must be of earthenware or porcelain, and care must be taken not to use too much iodine, especially when abrasions are present.
13. (L'UNION MeDICALE.) Oxide of zinc, 2 parts; tannic acid, 1 part; glycerin, 10 parts; balsam of Peru, 8 parts; camphor, 4 parts.
14. (SWEDIAUR'S PASTE.) Bitter almonds, 8 oz.; honey, 6 oz.; powdered camphor and flour of mustard, of each 1/2 oz.; burnt alum and olibanum, of each 1/2 oz.; yolks of 3 eggs; beat to a paste. To be applied night and morning.
15. (VANCE'S CREAM.) Ointment of nitrate of mercury, 1 oz.; camphor, 1 dr.; oil of turpentine, 2 dr.; oil of olives, 4 dr.; mix well together. To be applied by gentle friction 2 or 3 times daily.
_Obs._ All the preceding preparations are intended for chilblains before they break. The liniments of ammonia, camphor, opium, soap, and turpentine, as well as the compound camphor liniment of the British Pharmacopia, are also excellent preparations for the same purposes.
=CHIL'DREN (Care of).= See INFANCY.
=Children (Diseases of).= See the respective heads, and DISEASES.
=CHIL'LIES.= See CAPSIc.u.m, PEPPERS.
=CHIM'NEYS= were not introduced into England until the reign of Queen Elizabeth, and for a considerable period the principles of their construction were ill-understood. When the air inside and outside a chimney is at the same temperature, an equilibrium exists; there is no draught in the chimney, because the downward tendency of that within is counteracted by the upward pressure of that without. Let a fire be kindled in the grate; hot air is evolved, the chimney is heated, the air it contains suffers expansion, and a portion is expelled. The chimney now contains a smaller weight of air than it did before; the external and internal columns no longer equibalance each other, the warmer and lighter air is forced upwards from below, and its place is occupied by cold, and consequently heavier air. If the fire continues to burn, and the chimney retains its temperature, the second portion of air is disposed of like the first, and the ascending current continues, so long as the sides of the chimney are hotter than the surrounding air. Should the reverse happen to be the case, as sometimes occurs from sudden atmospheric changes, the column of air within the chimney rapidly contracts in volume, the deficiency is filled up from without, the column of air becomes heavier than one of a corresponding height on the outside of it, or in the apartment, and, obeying the common laws of gravitation, it falls out of the throat of the chimney or fire-place just as a heavy body sinks in water, and has its place occupied by air from above. In this way a descending current, of more or less intensity and duration, is established, and, if there is a fire in the grate, the chimney "smokes,"
or, if the grate is empty, perhaps the smoke from neighbouring chimneys finds its way into our apartments. By the judicious arrangement of the fire-place, and the throat and flue of a chimney, an upward current may be constantly ensured so long as there is a fire in the grate, or the air of the apartment is warmer than the external atmosphere.
Count Rumford was the first who scientifically investigated the construction of chimneys. He showed that more heat is obtained from the fire by reflection when the coverings are placed in an oblique position.
He also directed that the fire itself should be kept as near to the hearth as possible, and that the throat of the chimney should be constructed much narrower than was then the practice, in order to prevent the escape of so much heated air as happened with wide throats. By contracting the open part of the fire-place immediately over the fire, as by lessening the width of the hobs, or by bringing the throat of the chimney closer to the fire, and by contracting the throat of the chimney itself, within certain limits, any desired amount of draught may be obtained. When the s.p.a.ce above the fuel is too small, the throat too near the burning fuel, or the throat itself too contracted, the draught of a common chimney is often too strong, and much fuel and heat is wasted. When the reverse is the case, the draught is commonly too languid, the fire draws badly, a portion of the smoke escapes into the room, and all the usual annoyances of a smoky chimney are suffered. By a proper attention to these conditions a common fire-place may be adapted for the combustion of bituminous or easy burning coal, or of anthracite, and varieties of coal that require a considerable draught. It may even be converted into a wind furnace; whilst the inconvenience of smoky chimneys may be always avoided, and, when existing, easily cured. This is presuming, however, that a sufficient supply of air exists in front of the fire-place (_i.e._ in the apartment), not only for the combustion of the fuel, but also for the upward current of the chimney. Many chimneys smoke simply from the apartment being so ill-ventilated that the supply here alluded to is not provided. It may be further stated, as a rule, that the greater the length of a chimney the stronger will be the draught. Hence, the chimneys of the upper rooms of a house often smoke, whilst the fires in the rooms beneath them burn pleasantly and vigorously. Such cases are commonly relieved by a chimney-pot or cowl, of which numerous varieties are now before the public. The more crooked or tortuous the course of a chimney the less likely is it to be affected by eddies and gusts of wind from neighbouring buildings or hills. See FIRE, GRATE, SMOKE PREVENTION, STOVE.
=CHI'NA.= In the purchase of china, gla.s.s, and earthenware, care should be taken to select those patterns which in case of breakage can be the most readily matched. Peculiar or rare patterns should be avoided, for if any such be broken, it will generally be found very difficult and expensive, and frequently impossible, to replace them.
China, gla.s.s, and earthenware, when very dirty, are best cleaned with finely powdered fuller's earth and warm water, followed by rinsing in clean water. A little clean soft soap may be added to the water instead of fuller's earth. See PACKING, PORCELAIN.
=CHIN'OIDINE.= See QUINOIDINE.
=CHINOLINE BLUE.= See CYANINE.
=CHINTZ (to Wash).= Boil 2 lbs. of rice in two gallons of water till soft; and pour the mixture into a tub; let it stand until it attains a warmth generally used for coloured linens; then put the chintz in it, and wash it with the rice instead of soap, until all the dirt has disappeared. Next boil another 2 lb. of rice, as above, in another two gallons of water, but strain the rice from the water, and mix it in warm water. Wash the chintz in this till quite clean, and afterwards rinse it in the water the rice was boiled in. This will answer the same end as starch, as no wet will affect it, as it will be stiff while it is worn. If a gown, it must be taken to pieces; and when dried, it must be hung as smooth as possible, after which it must be dry-rubbed with a smooth stone, but no iron must be used.
=CHIRETTA.= CHIRATA. The entire plant (_Ophelia chirata_) is employed in medicine. Northern India. The plant is pulled up by the root when the flowers begin to decay, and the capsules are formed. The dried plant, sometimes with, but more commonly without, the root, is the form in which the chiretta is generally met with in commerce. The whole plant is intensely bitter, but is without odour. In its physiological action it bears a great resemblance to gentian. Instead of a constipating, it appears to possess a slightly relaxing effect. It is an excellent stomachic and carminative, and is said to diminish the tendency to acidity, and to be of great service in the dyspepsia accompanying gout. No vegetable alkaloid has been obtained from it. If given in powder, the dose of chiretta is twenty grains. It is, however, more generally given in the form of an infusion or tincture (which _see_).
=CHI'TIN.= This name has been given to the hard, insoluble matter forming the sh.e.l.ls and elytra of insects. It is obtained by boiling the elytra of the c.o.c.kchafer with water, alcohol, ether, acetic acid, and alkalies.
=CHIT'TICK'S REMEDY.= Dr Chittick's remedy for stone consisted of a fixed alkali, administered in veal broth. (Paris.)
=CHLORAL.= C_{2}HCl_{3}O. A peculiar liquid first obtained by Liebig, by the action of chlorine on alcohol. The name was intended to express its origin from chlorine and alcohol.
_Prep._ (Liebig.) Anhydrous alcohol is placed in a tubulated retort, and dry chlorine gas pa.s.sed through it, at first in the cold, but afterwards with the application of a gentle heat, until the chlorine pa.s.ses unchanged through the liquor on raising it to the boiling temperature; on cooling, the whole forms a crystalline ma.s.s of what was at one time thought to be chloral hydrate, but which subsequent researches have shown to be chloral alcoholate; this is melted by a gentle heat, and agitated with three times its volume of oil of vitriol; on increasing the heat a little, an oily stratum of impure chloral rises to the surface. It is purified by boiling it for some time (to drive off free hydrochloric acid and alcohol), next distilling it with an equal volume of oil of vitriol; and lastly, rectifying it from some powdered quick-lime, the process being stopped as soon as the surface of the lime becomes dry.
_Prop., &c._ Chloral is an oily liquid, possessing an ethereal smell; it is soluble in alcohol, ether, and water; with a small quant.i.ty of the latter it rapidly changes into a semi-solid crystalline ma.s.s (chloral hydrate), which is soluble in a larger quant.i.ty of water; boils at 201; sp. gr. 1502. It is decomposed by the caustic earths and alkalies. By age it is converted into a white, solid, translucent substance (insoluble chloral), which is reconverted by heat and by sulphuric acid into ordinary chloral.
_Obs._ In operating as above the chlorine is most conveniently introduced by a tube inserted into the tubulature of the retort, and a long tube, bent upwards, should be connected with the beak to convey away the hydrochloric acid gas extricated, and to allow the volatilised alcohol and chloral to condense, and flow back into the retort.
=Chloral, Camphorated.= Hydrate of chloral and camphor, equal parts. Rub them together in a warm mortar until they liquefy. It forms clear mixtures with oil of turpentine and chloroform, but not with solution of ammonia.
It is a counter-irritant, and applied externally it has been found to give relief in rheumatic pains and neuralgia. It should be painted on the affected part with a camel's-hair brush.
=Chloral, Hydrate.= C_{2}HCl_{3}O. Aq. _Syn._ HYDRATE OF CHLORAL. _Prep._ "Pa.s.s dry chlorine gas, for several days, through absolute alcohol, sp.
gr. 0795, until it becomes a thick viscid liquid of sp. gr. 157. At the beginning of the operation the alcohol is well cooled to prevent inflammation and explosion, but towards the end of the operation the alcohol is heated nearly to the boiling point. The resulting liquid, which after a day or two solidifies to a ma.s.s of crude chloral hydrate, is agitated with four times its bulk of concentrated sulphuric acid, and the anhydrous chloral which floats on the surface is separated and purified by fractional distillation. The purified anhydrous chloral is placed in a still, mixed with 11 per cent. of water, and distilled over chalk to remove any hydrochloric acid that may be present; the resulting solid distillate is then fused and poured out into shallow vessels to cast into cakes." (Squire.) The purest chloral hydrate is said to be that which has been crystallised two or three times out of pure bisulphide of carbon.--_Prop._ White opaque solid, having a pungent odour resembling that of a ripe melon. Soluble in water, glycerin, and alcohol. Gradually volatilises in the air, and may be distilled without decomposition. From 100 gr. dissolved in 1/2 fl. oz. of water, well shaken with 1 fl. oz. of solution of potash (B. P.), and allowed to stand for several hours, at least 46 grain-measures of chloroform should separate.
Chloral hydrate may be obtained in crystals by mixing the cake with about half its bulk of chloroform, and putting aside in a cool place. When the crystallisation is complete (which is generally in about 8 or 10 days) the crystals are freed from the mother liquor by a centrifugal machine, and afterwards dried at a gentle heat. The mother liquor may be utilised for future crystallisations.
_Uses._ An excellent sedative, antispasmodic, hypnotic, anodyne. It has done good service in hypochondriacal and other nervous affections, as well as in the insomnia of the insane, and of dipsomaniacs; also in asthma, hooping-cough, and scarlet fever. It has also the reputation of being an efficient preventive of sea-sickness, especially on short voyages, such as crossing the channel, which can be accomplished during the sleep occasioned by the agent.--_Dose_, from 10 to 60 gr.
It was introduced into medical practice by Dr Liebreich, of Berlin.
Immense quant.i.ties are imported into this country from Germany.
=CHLORALUM.= An impure aqueous solution of chloride of aluminum, sp. gr.
115, 1 fl. oz. of the liquid contains 75 grains of anhydrous chloride.
Introduced by Professor Gamgee as an antiseptic and disinfectant, for which purposes it is recommended to dilute the article as sold with four times its bulk of water.