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In discussing fur dyeing, the question naturally arises, "Why dye furs at all? Are not furs most attractive in their natural colors, and therefore more desirable than those which acquire their color through the artifices of man?" The answer cannot be given simply. Natural furs of the more valuable kinds are indeed above comparison with the majority of dyed furs.
Yet there are several reasons which fully justify and explain the need for fur dyeing, for at the present time, this branch of the fur industry is almost as important and indispensable as the dressing of furs.
The first application of dyeing to furs, had for its purpose the improvement of skins which were poor or faulty in color; or rather, the object was to hide such defects. As nearly as can be ascertained, this practise was inst.i.tuted at some time during or before the fourteenth century, for fur dyeing seems to have been common during that period, as is apparent from the verses of a well-known German satirist, Sebastian Brant, who lived in the latter part of the fourteenth century:
"Man kann jetzt alles Pelzwerk farben, Und tut es auf das schlechste gerben."
However, at a later period, there was a general condemnation of the dyeing of furs, and among the list of members of the furrier's guilds, none can be found who are described as dyers. There is a record of a decree issued by a prince in a German city in the sixteenth century, prohibiting the practise of fur dyeing. Inasmuch as furs were worn only by the n.o.bility and certain other privileged cla.s.ses, and also were very costly, there was great profit to be had by dyeing inferior skins so as to disguise the poor color, and then selling such furs at the price of superior quality skins. This was undoubtedly the reason for the prohibitory decree, but there were some who continued to practise the forbidden art in secret, using secluded and out-of-the-way places for their workshops, and mixing their carefully-guarded recipes with as much mystery as the witches did their magic potions. These circ.u.mstances probably account for the great amount of mystery which has been, and still is to a considerable degree, attached to fur dyeing, and also explains the opprobrium and distrust with which fur dyers were formerly regarded.
Even at the present time, dyeing is often employed to improve furs which are faulty in color. It frequently happens, that in a lot of skins there are some which are considerably off shade, or in which the color is such as to appreciably reduce their value below the average, the hair being usually too light a shade, or of uneven coloring. By carefully dyeing these skins of inferior color, they can be made to match very closely the best colored skins of the particular lot of furs, and consequently increase their value. With most of the cheaper kinds of furs, the trouble and cost of improvement by dyeing would not be worth while today; but with some of the more valuable furs, and especially such as are very highly prized, like the Russian sable, or marten, or chinchilla, the darkening of light skins by the skillful application of fast dyes to the extreme tips of the hair, will increase their value sufficiently to warrant the expense. This dyeing or "blending" as it is called in such cases, is done in such a clever and artistic manner that only experts can distinguish them from the natural. Dyeing used for such purposes is not objectionable, provided the skins are sold as dyed or "blended."
There are certain kinds of furs, such as the various lambs, Persian, Astrachan, Caracul, etc., which are never used in their natural color, because it is usually of a rusty brownish-black. These are furs possessing valuable qualities otherwise, so they are dyed a pretty shade of black, which brings out the beauty of the fur to the fullest extent. Sealskins are also dyed always. Formerly they were dyed a deep, rich dark brown, resembling the finest shades of the natural color, but now the seals are dyed black with a brownish undertone, a color quite different from the natural. While these two instances cannot be said to be cases of dyeing to disguise faulty color, they are examples of improvement of color by dyeing.
Closely a.s.sociated with the use of dyes to increase the value of a fur by improving its color, is the dyeing of skins of a certain lot of furs to produce a uniform shade, thereby facilitating or to a considerable degree eliminating the task of matching the skins by the furrier. This is usually done only on skins which are quite small, of which a great many are needed in the manufacture of fur garments, because the matching of several hundred skins would entail too much time and labor commensurate with the value of the fur. The most notable instance of the use of dyes to produce a uniform shade on furs is the case of the moleskin. Occasionally, furs are dyed after being made into garments, by careful application of dyes, in order to obtain certain harmonious effects, such as uniformity of stripe, or to produce a desired gradation of shade among the different skins comprising the garment.
Not infrequently, the great variety of shades and color schemes which Nature provides in the different furs, becomes insufficient to satisfy the desire of the fur-wearing public for something new. The whims of fas.h.i.+on always require some novel effect, even though it be for only one season.
To meet this demand for novelty, fantasy or mode shades are produced on suitable furs,--colors which do not imitate those of any animal at all, but which, nevertheless, strike the popular fancy. It often happens that such a color becomes quite popular, and enjoys a considerable vogue, to the great profit of those who introduced the particular color effect. The best ones, however, meet with only a comparatively short-lived demand, being soon superseded by different color novelties.
The basis, though, of the greatest proportion of fur dyeing at the present time, is the imitation of the more valuable furs on cheaper or inferior skins. With the gradual popularization of furs as wearing apparel since the beginning of the last century, the demand for furs of all kinds has increased enormously. The supply of furs, on the other hand, and especially of the rarer kinds, has had difficulty in keeping pace with the requirements, and as a result there is a shortage. A very effective means of relieving this shortage, to a great degree, at any rate, is the dyeing of imitations of the scarcer furs on cheaper skins. There are many animals among the more common, and more easily obtainable ones, whose skins are admirably suited as the basis of imitations of the more costly furs. Some of the furs which are adapted for purposes of dyeing imitations are marmot, red fox, rabbit, hare, muskrat, squirrel, opossum, racc.o.o.n, and many others, and the imitations made are those of mink, sable, marten, skunk, seal, chinchilla, etc., and indeed, there are very few valuable furs, which have not been dyed in imitation on cheaper pelts.
On account of the general mystery which formerly surrounded fur dyeing establishments, and which has persisted to this day, although to a lesser degree, many peculiar notions were held, even by those in the fur trade, concerning the production of imitations. The idea that in order to "make"
a certain fur out of a cheaper skin, it was necessary to use the blood of the animal imitated, is typical of the conceptions of fur dyeing held not so long ago. To-day, while the knowledge generally possessed about this branch of the fur industry is meagre and vague, the air of mystery and secrecy has become somewhat clarified, and such ideas as are current about fur dyeing are more rational than formerly.
The dyeing of imitations is quite an artistic kind of work, and indeed fur dyeing ought to be cla.s.sed among the finest of industrial arts. Some of the reproductions achieved by dyers on a commercial scale are truly admirable. The possibility of imitating the finer furs on cheaper skins naturally led to abuse, the dyed furs being pa.s.sed off frequently on the unsuspecting and uninformed buyer as the genuine original. In fact, this practise became so flagrant that in England laws were enacted to remedy the evil. At the present time, dyed furs are all sold as such, although there always may be some unscrupulous merchants who seek to profit by deception. Some of the imitations and the names of the furs for which they were sold, are as follows:
Muskrat, dyed and plucked sold as seal Nutria, plucked and dyed sold as seal Nutria, plucked and natural sold as beaver Rabbit, sheared and dyed sold as seal or electric seal Otter, plucked and dyed sold as seal Marmot, dyed sold as mink or sable Fitch, dyed sold as sable Rabbit, dyed sold as sable Rabbit, dyed and sheared sold as beaver Muskrat, dyed sold as mink or sable Hare, dyed sold as sable, fox, or lynx Wallaby, dyed sold as skunk White rabbit, natural sold as ermine White rabbit, dyed sold as chinchilla White hare, dyed or natural sold as foxes, etc.
Goat, dyed sold as bear, leopard, etc.
This list serves to indicate but a few of the great number of possibilities which are available for the fur dyer to produce imitations of the better cla.s.ses of furs. Needless to say, these imitations cannot, as a general rule, equal the originals, because while the color is one of the most important features in judging the fur, the nature of the hair, gloss, waviness, thickness, and also the durability are essential considerations, and it is only in certain instances that skins used for imitations approach the originals in these respects. However, for the purposes and desires of the majority of people who wear furs, the imitations are deemed quite satisfactory, and they also have the advantage of being cheaper than the natural originals.
For whichever reason furs are dyed, there is no doubt that the art of fur dyeing is one of the most difficult kinds of application of dye materials.
In the dyeing of the various textiles, either as skein or woven fabric, the material is of a uniform nature, and therefore the dye is absorbed evenly by the fibres. Moreover, textiles are dyed at, or near the boil, the dyestuff being more uniformly and permanently taken up from solution by the fibre at elevated temperatures.
How different is the case with furs! Far from being h.o.m.ogeneous, furs present the greatest possible diversity of fibres to be dyed. As already noted elsewhere, fur consists of two princ.i.p.al parts, the hair and the leather, differing widely in their actions toward dyes. As a general rule, the leather absorbs dyestuffs much more readily than the pelage, and inasmuch as fur dyeing is intended mainly and primarily to apply to the hair, there is usually an appreciable loss of dye material due to its being absorbed by the leather, and thereby rendered unavailable for dyeing the hair. This fact must be taken into account in the dyeing of furs, and the methods must be adapted accordingly.
With reference to the hair itself, not only has each cla.s.s of furs hair of a different kind, but even in the same group there is always a considerable divergence in the properties of the hair. The fur-hair, being more or less of a woolly nature, takes up the dye with comparative ease, while the top-hair is quite resistant to the action of all dye materials.
As pointed out in the discussion of the nature of fur, on different parts of the same pelt the hair varies in its capacity for absorbing coloring matters. The color of the hair, also frequently presents a great variety throughout the skin, both in fur-hair and top-hair. Yet with all this lack of uniformity and h.o.m.ogeneity, the dyed fur must be of an even color, closely approaching the natural, gently graded and without any harsh or unduly contrasted effects. The natural gloss of the hair, one of the most valuable qualities of the fur, must be preserved. This is by no means a simple matter, for the l.u.s.ter is affected by dyes and chemicals with comparative ease, and especially careful treatment is necessary to prevent any diminution of the gloss.
When the leather part of the fur is exposed to solutions of a temperature exceeding 4050 centigrade, it soon shrivels up or shrinks, and on drying the pelt, becomes hard and brittle, and therefore quite useless.
Methods of fur dyeing have to take into consideration this fact, and the temperature of the dyebath must not be greater than 3540 centigrade. To be sure, certain dressings make furs capable of withstanding much higher temperatures, but their applicability is not universal, being suited only for a very limited special cla.s.s of dyestuffs. (V. Fur Dressing). The necessity for employing comparatively low temperatures, coupled with the great resistance of the hair to the absorption of dye, even at much higher temperatures, makes fur-dyeing a very difficult operation indeed. Another obstacle which must be surmounted, is the possibility of extraction by the dye solution, of those materials, chemical or otherwise, which are contained in the leather, and which are the basis of its permanence, softness and flexibility. For in the majority of dressing processes, the action of the ingredients is a preservative one, and when these are wholly or partially removed from the leather during the dyeing, it becomes, on drying, hard and h.o.r.n.y, like the original undressed pelt. In cases where furs are to be dyed, special dye-resisting dressings must be used, or the dyed skins must receive an additional dressing before drying.
Dyeings on furs, to have any value, must possess great fastness to light, rubbing and wear, and must not change color in time, either when the furs are stored, or when made up into garments. The necessity for fur dyeings to have these properties, together with the difficulties outlined above, has greatly limited the field of available dyeing materials, as well as the methods of application. These will now be taken up in detail.
CHAPTER IX
FUR DYEING
GENERAL METHODS
Before the furs can be dyed, they have to undergo certain preparatory processes: first, killing, which renders the hair more susceptible to the absorption of the dye; and second, mordanting, which consists in treating the killed fur with chemicals which help the dye to be fixed on the hair.
Then the skins are ready to be dyed.
There are two princ.i.p.al methods by which dyes are applied to furs in practise: the brush process, whereby only the tips or the upper part of the hair are colored; and the dip process, whereby the entire fur, including the leather is dyed. All other procedures in fur dyeing are modifications or combinations of these two. Killing solutions and mordanting solutions are also applied by one of these methods, usually the dip process, although very frequently combinations of the brush and dip methods are used.
Chronologically the brush method of dyeing came first. The early masters of the art were extremely fearful about employing any means by which there was a possibility of the leather being in any way affected. They naturally had to devise such methods as would give the desired effect in a satisfactory manner, and as would be confined solely to the hair part of the fur, leaving the leather untouched. By applying the dye or other material to be used, in the form of a paste with a brush, the upper portion of the hair only was treated. For different kinds of furs different sorts of brushes were used, and the depth to which the hair was colored could be controlled by skillful manipulation of the brushes. It was frequently necessary to give a ground color to the hair, the lower part being dyed a different shade from the tips. This was accomplished by spreading the dye paste over the hair with a broad brush, and then beating the color in with a specially adapted beating brush. With larger furs, two skins were placed hair to hair after the dye had been brushed on, and the color forced to the bottom of the hair by a workman tramping on the skins. The dyeing of seal was a typical ill.u.s.tration of these procedures. First the tips of the hair were dyed. The color was brushed on, allowed to dry, then the excess beaten out with rods. These operations were repeated until the proper depth of shade was obtained, often as many as a dozen or more applications of the dye being necessary. Then the base color was spread over the hair, and beaten or tramped in until the lower parts of the hair were penetrated. This process also required drying and beating out of the excess dye, as well as numerous applications of the dye to impart the desired color to the hair. Prior to the dyeing, the furs were killed, by brus.h.i.+ng on a paste containing the essential ingredients, drying and beating and brus.h.i.+ng the fur, just the same as in dyeing. It will be readily seen that such methods were exceedingly laborious, and in some cases the dyeing took many weeks, and even months.
It was quite a step forward when a certain fur dyer, possessing a little more courage, or perhaps, experimenting spirit than the others, attempted to dye furs by dipping them entirely into a bath containing a solution of the dye instead of applying a paste as formerly. The advantages to be gained by such a method of dyeing were many. A large number of skins could be treated thus at one time, and this was a very important consideration in view of the great increase in the demand for dyed furs. By allowing the furs to remain in the dye solution until the proper shade was obtained, the time and labor of applying many coats of dye by brush was considerably reduced, and in addition, there was a greater probability of the products coming out all alike, uniformly dyed. The results as far as the hair was concerned, were indeed highly gratifying, but the condition of the leather after dyeing was not so encouraging. This difficulty has to a considerable degree been overcome, although there are frequent instances of the leather being affected by the dyeing process even with modern methods. However, the remedy in such cases, or rather the preventative is the proper dressing of the skins prior to the dyeing. The dip method of dyeing has acquired great importance, and is being employed in dyeing operations involving the handling of millions of skins annually. In certain instances, nevertheless, the brush method is of prime significance as in the dyeing of seal, and seal imitations on muskrat and coney, enormous quant.i.ties of furs being dyed in this fas.h.i.+on. In the majority of imitations dyed, both the brush and the dip methods must be used.
Figure 19 ill.u.s.trates the various types of brushes which are used at the present time for the application of the dye by the brush method. Each brush has a specific purpose and use. The procedure in brush dyeing is somewhat as follows. The skins, after being properly treated, that is, killed, and mordanted, are placed on a table, or work-bench, hair-side up.
Then by means of a brush which is adapted to the nature and requirements of the particular fur, the solution is brushed on in the direction of the fall of the hair, occasionally beating gently with the brush so as to cause the dye to penetrate to the desired depth. Considerable skill and care must be exercised in this operation as it is rather easy to force the dye down further than is wanted, and in some cases the leather or the roots of the hair may be affected. The skin having received its coat of dye, is then dried and finished, if no other dyeing processes are to be applied. Frequently, with certain types of dyes, several applications of color are necessary, and these are brushed on as the first one, drying each time. Then, on the other hand, the skin may receive a dyeing in the bath by dipping, and for this also, the fur is first dried after the brush dyeing.
[Ill.u.s.tration: FIG. 19. BRUSHES USED IN FUR DYEING BY THE BRUSH METHOD.]
Quite recently, owing to the great quant.i.ties of furs which are being dyed as seal imitations, chiefly by the brush method, although the dip method is used in conjunction with it, machines have been invented to replace the hand brush, and the dye is now applied mechanically. Machines for this purpose are by no means new, there being records of inventions almost a score of years past, but they did not achieve much success.
Brush-dyeing machines, to be efficient, must be designed to suit the needs of the particular type of fur to be dyed, otherwise there will be a great lack of uniformity in the dyed skins, a condition which cannot occur when the dye is brushed on by hand brushes. Figure 20A and B shows diagrammatically, machines invented within the past few years, which are used to dye mechanically furs by the brush process.
[Ill.u.s.tration: FIG. 20. TYPES OF MACHINES FOR DYEING FURS BY THE BRUSH METHOD.
_A._ (U. S. Patent 1,225,447.) _B._ (U. S. Patent 1,343,355.)]
[Ill.u.s.tration: FIG. 21. DRUM FOR WORKING WITH LIQUIDS.
(_Turner Tanning Machinery Co., Peabody, Ma.s.s._)]
For the dipping process, the dye solution is prepared in vats, or liquid-tight drums, or in some instances in paddle arrangements. The skins are placed in the dye-bath, and the dyeing operation proceeds without any difficulty. After the proper shade is obtained, the furs are removed, washed free of excess dye, dried and finished. The dipping method is employed where a single shade is to be dyed on the fur, as the production of blacks on lambs. But in most cases, the dyeing in the bath is supplemented by the application of a coat of dye by the brush to the upper part of the hair, the color being usually a darker shade than the ground dyeing. Thus, for example, in the dyeing of imitation sable on kolinsky or a similar fur, the skins are first dyed the relatively light color of the under-hair by the dip process, then the dark stripe effect is brushed on.
The blending of sables, martens, chinchillas or other rare furs, is not done in the same manner as with other furs, because each skin requires individual attention and a long and careful treatment. The dye solution is applied by means of very fine brushes or sometimes feathers, to the extreme tips of the hair, until the proper degree of color intensity is obtained. The time, labor, and skill necessary for this sort of work are warranted only in the case of the highest-priced furs, and the blendings are so excellent as to defy detection, except by experts.
[Ill.u.s.tration: FIG. 22. DEVICE FOR CONVEYING SKINS.
(_Turner Tanning Machinery Co., Peabody, Ma.s.s._)]
After the furs have gone through all the operations required by the processes of killing, mordanting, dyeing and was.h.i.+ng, they are ready to be dried and finished. The procedure is quite similar to that employed in fur dressing. Sometimes the leather side of the skins is brushed with a strong salt solution before drying, in order to replace some of the salt which was extracted during the dyeing processes. In other instances, a light coat of some oily substance is brushed on, to render the leather soft and flexible after drying, where there is a possibility of the skins turning out otherwise. Great care must be exercised in the handling of the dyed skins to avoid the formation of stains or spots on the hair, which might ruin the dyeing. As little handling of the furs as is feasible will reduce any trouble from this source. In conveying the wet skins from one part of the plant to another it is desirable to use a device such as is shown in Fig. 22. For drying, the same machines as described under Fur Dressing can be used, and similar care must be taken to avoid overheating or irregularity of drying. Drum-cleaning const.i.tutes a very important operation in the finis.h.i.+ng of the skins, the hair receiving a polish, and the full l.u.s.tre and brilliancy of the dye being thereby brought out. Then after caging to remove the sawdust or sand, the skins are pa.s.sed over the staking knife, or are treated in a machine suited for the purpose, to stretch them and to render them thoroughly soft and flexible. And therewith is concluded the work of the fur dyer proper, and the skins are ready to return to the furrier, in whose hands they undergo the metamorphosis into the fur garments to be worn chiefly by the feminine portion of humanity.
CHAPTER X
FUR DYEING
"KILLING" THE FURS
If dressed furs are treated with a paste or solution of a dye properly prepared, and at the right temperature, the hair will show very little tendency to absorb the coloring matter. Even after prolonged treatment with the dye, only a small amount will be taken up by the hair, and in a very irregular fas.h.i.+on. Soft, woolly hair, like that of lambs and goats will be colored more easily than that of furs with harder hair, and the under-hair of a fur will generally have a greater affinity for the dye than the harder and stiffer top-hair. Moreover, in some parts of the same fur, the hair will absorb more color than in other parts. In other words, the hair of furs resists the action of dye materials to a greater or less degree, depending upon the character of the fur, and also upon the part of the pelt. In order to overcome this resistance of the hair, and to render it uniformly receptive to the coloring substances, the furs are treated with certain chemical agents, the process being known technically as "killing."
The origin of the term is obscure, but it is interesting to note that in the fur dyeing countries other than the United States and England, the corresponding expression is used: in Germany, "toten," and in France "tuer." The explanation of the process is as follows: The surface of the hair is covered with a fine coat of fatty material which renders the hair more or less impervious to dye solutions and solutions of other substances which may be used for dyeing purposes. This fatty coating of the hair cannot be removed by mechanical means, otherwise the hair would have been freed of it during the dressing operations. Chemical solvents must therefore be resorted to, and naturally alkaline materials are used, these being usually cheapest and also most effective in their dissolving action on fatty substances. Alcohol, ether, benzine, and other similar liquids also serve as killing agents on furs, since they too, are fat solvents.