Conversations on Chemistry Part 11

CONVERSATION III.

CONTINUATION OF THE SUBJECT.

MRS. B.

In our last conversation, we began to examine the tendency of caloric to restore an equilibrium of temperature. This property, when once well understood, affords the explanation of a great variety of facts which appeared formerly unaccountable. You must observe, in the first place, that the effect of this tendency is gradually to bring all bodies that are in contact to the same temperature. Thus, the fire which burns in the grate, communicates its heat from one object to another, till every part of the room has an equal proportion of it.

EMILY.

And yet this book is not so cold as the table on which it lies, though both are at an equal distance from the fire, and actually in contact with each other, so that, according to your theory, they should be exactly of the same temperature.

CAROLINE.

And the hearth, which is much nearer the fire than the carpet, is certainly the colder of the two.

MRS. B.

If you ascertain the temperature of these several bodies by a thermometer (which is a much more accurate test than your feeling), you will find that it is exactly the same.

CAROLINE.

But if they are of the same temperature, why should the one feel colder than the other?

MRS. B.

The hearth and the table feel colder than the carpet or the book, because the latter are not such good _conductors of heat_ as the former.

Caloric finds a more easy pa.s.sage through marble and wood, than through leather and worsted; the two former will therefore absorb heat more rapidly from your hand, and consequently give it a stronger sensation of cold than the two latter, although they are all of them really of the same temperature.

CAROLINE.

So, then, the sensation I feel on touching a cold body, is in proportion to the rapidity with which my hand yields its heat to that body?

MRS. B.

Precisely; and, if you lay your hand successively on every object in the room, you will discover which are good, and which are bad conductors of heat, by the different degrees of cold you feel. But, in order to ascertain this point, it is necessary that the several substances should be of the same temperature, which will not be the case with those that are very near the fire, or those that are exposed to a current of cold air from a window or door.

EMILY.

But what is the reason that some bodies are better conductors of heat than others?

MRS. B.

This is a point not well ascertained. It has been conjectured that a certain union or adherence takes place between the caloric and the particles of the body through which it pa.s.ses. If this adherence be strong, the body detains the heat, and parts with it slowly and reluctantly; if slight, it propagates it freely and rapidly. The conducting power of a body is therefore, inversely, as its tendency to unite with caloric.

EMILY.

That is to say, that the best conductors are those that have the least affinity for caloric.

MRS. B.

Yes; but the term affinity is objectionable in this case, because, as that word is used to express a chemical attraction (which can be destroyed only by decomposition), it cannot be applicable to the slight and transient union that takes place between free caloric and the bodies through which it pa.s.ses; an union which is so weak, that it constantly yields to the tendency which caloric has to an equilibrium. Now you clearly understand, that the pa.s.sage of caloric, through bodies that are good conductors, is much more rapid than through those that are bad conductors, and that the former both give and receive it more quickly, and therefore, in a given time, more abundantly, than bad conductors, which makes them feel either hotter or colder, though they may be, in fact, both of the same temperature.

CAROLINE.

Yes, I understand it now; the table, and the book lying upon it, being really of the same temperature, would each receive, in the same s.p.a.ce of time, the same quant.i.ty of heat from my hand, were their conducting powers equal; but as the table is the best conductor of the two, it will absorb the heat from my hand more rapidly, and consequently produce a stronger sensation of cold than the book.

MRS. B.

Very well, my dear; and observe, likewise, that if you were to heat the table and the book an equal number of degrees above the temperature of your body, the table, which before felt the colder, would now feel the hotter of the two; for, as in the first case it took the heat most rapidly from your hand, so it will now impart heat most rapidly to it.

Thus the marble table, which seems to us colder than the mahogany one, will prove the hotter of the two to the ice; for, if it takes heat more rapidly from our hands, which are warmer, it will give out heat more rapidly to the ice, which is colder. Do you understand the reason of these apparently opposite effects?

EMILY.

Perfectly. A body which is a good conductor of caloric, affords it a free pa.s.sage; so that it penetrates through that body more rapidly than through one which is a bad conductor; and consequently, if it is colder than your hand, you lose more caloric, and if it is hotter, you gain more than with a bad conductor of the same temperature.

MRS. B.

But you must observe that this is the case only when the conductors are either hotter or colder than your hand; for, if you heat different conductors to the temperature of your body, they will all feel equally warm, since the exchange of caloric between bodies of the same temperature is equal. Now, can you tell me why flannel clothing, which is a very bad conductor of heat, prevents our feeling cold?

CAROLINE.

It prevents the cold from penetrating . . . . . . . .

MRS. B.

But you forget that cold is only a negative quality.

CAROLINE.

True; it only prevents the heat of our bodies from escaping so rapidly as it would otherwise do.

MRS. B.

Now you have explained it right; the flannel rather keeps in the heat, than keeps out the cold. Were the atmosphere of a higher temperature than our bodies, it would be equally efficacious in keeping their temperature at the same degree, as it would prevent the free access of the external heat, by the difficulty with which it conducts it.

EMILY.

This, I think, is very clear. Heat, whether external or internal, cannot easily penetrate flannel; therefore in cold weather it keeps us warm; and if the weather was hotter than our bodies, it would keep us cool.

MRS. B.

The most dense bodies are, generally speaking, the best conductors of heat; probably because the denser the body the greater are the number of points or particles that come in contact with caloric. At the common temperature of the atmosphere a piece of metal will feel much colder than a piece of wood, and the latter than a piece of woollen cloth; this again will feel colder than flannel; and down, which is one of the lightest, is at the same time one of the warmest bodies.

CAROLINE.

This is, I suppose, the reason that the plumage of birds preserves them so effectually from the influence of cold in winter?