Conversations on Chemistry Part 33

MRS. B.

Yes: if about one part of oxygen gas be mixed with about four parts of nitrogen gas, atmospherical air is produced.*

[Footnote *: The proportion of oxygen in the atmosphere varies from 21 to 22 per cent.]

EMILY.

The air, then, must be an oxyd of nitrogen?

MRS. B.

No, my dear; for there must be a chemical combination between oxygen and nitrogen in order to produce an oxyd; whilst in the atmosphere these two substances are separately combined with caloric, forming two distinct gases, which are simply mixed in the formation of the atmosphere.

I shall say nothing more of oxygen and nitrogen at present, as we shall continually have occasion to refer to them in our future conversations.

They are both very abundant in nature; nitrogen is the most plentiful in the atmosphere, and exists also in all animal substances; oxygen forms a const.i.tuent part, both of the animal and vegetable kingdoms, from which it may be obtained by a variety of chemical means. But it is now time to conclude our lesson. I am afraid you have learnt more to-day than you will be able to remember.

CAROLINE.

I a.s.sure you that I have been too much interested in it, ever to forget it. In regard to nitrogen there seems to be but little to remember; it makes a very insignificant figure in comparison to oxygen, although it composes a much larger portion of the atmosphere.

MRS. B.

Perhaps this insignificance you complain of may arise from the compound nature of nitrogen, for though I have hitherto considered it as a simple body, because it is not known in any natural process to be decomposed, yet from some experiments of Sir H. Davy, there appears to be reason for suspecting that nitrogen is a compound body, as we shall see afterwards.

But even in its simple state, it will not appear so insignificant when you are better acquainted with it; for though it seems to perform but a pa.s.sive part in the atmosphere, and has no very striking properties, when considered in its separate state, yet you will see by-and-bye what a very important agent it becomes, when combined with other bodies. But no more of this at present; we must reserve it for its proper place.

CONVERSATION VII.

ON HYDROGEN.

CAROLINE.

The next simple bodies we come to are CHLORINE and IODINE. Pray what kinds of substances are these; are they also invisible?

MRS. B.

No; for chlorine, in the state of gas, has a distinct greenish colour, and is therefore visible; and iodine, in the same state, has a beautiful claret-red colour. The knowledge of these two bodies, however, and the explanation of their properties, imply various considerations, which you would not yet be able to understand; we shall therefore defer their examination to some future conversation, and we shall pa.s.s on to the next simple substance, HYDROGEN, which we cannot, any more than oxygen, obtain in a visible or palpable form. We are acquainted with it only in its gaseous state, as we are with oxygen and nitrogen.

CAROLINE.

But in its gaseous state it cannot be called a simple substance, since it is combined with heat and electricity?

MRS. B.

True, my dear; but as we do not know in nature of any substance which is not more or less combined with caloric and electricity, we are apt to say that a substance is in its pure state when combined with those agents only.

Hydrogen was formerly called _inflammable air_, as it is extremely combustible, and burns with a great flame. Since the invention of the new nomenclature, it has obtained the name of hydrogen, which is derived from two Greek words, the meaning of which is, _to produce water_.

EMILY.

And how does hydrogen produce water?

MRS. B.

By its combustion. Water is composed of eighty-five parts, by weight, of oxygen, combined with fifteen parts of hydrogen; or of two parts, by bulk of hydrogen gas, to one part of oxygen gas.

CAROLINE.

Really! is it possible that water should be a combination of two gases, and that one of these should be inflammable air! Hydrogen must be a most extraordinary gas that will produce both fire and water.

EMILY.

But I thought you said that combustion could take place in no gas but oxygen?

MRS. B.

Do you recollect what the process of combustion consists in?

EMILY.

In the combination of a body with oxygen, with disengagement of light and heat.

MRS. B.

Therefore when I say that hydrogen is combustible, I mean that it has an affinity for oxygen; but, like all other combustible substances, it cannot burn unless supplied with oxygen, and also heated to a proper temperature.

CAROLINE.

The simply mixing fifteen parts of hydrogen, with eighty-five parts of oxygen gas, will not, therefore, produce water?

MRS. B.

No; water being a much denser fluid than gases, in order to reduce these gases to a liquid, it is necessary to diminish the quant.i.ty of caloric or electricity which maintains them in an elastic form.

EMILY.

That I should think might be done by combining the oxygen and hydrogen together; for in combining they would give out their respective electricities in the form of caloric, and by this means would be condensed.

CAROLINE.

But you forget, Emily, that in order to make the oxygen and hydrogen combine, you must begin by elevating their temperature, which increases, instead of diminis.h.i.+ng, their electric energies.

MRS. B.

Emily is, however, right; for though it is necessary to raise their temperature, in order to make them combine, as that combination affords them the means of parting with their electricities, it is eventually the cause of the diminution of electric energy.