Paint Technology and Tests Part 25

[Ill.u.s.tration: Corrosion Adhering to Film Stripped from Panel Painted with Gypsum (Calcium Sulphate)]

=Panel No. 31--Calcium Sulphate.= Under the paint film of gypsum, rust soon appeared, showing that the film was not a good excluder of moisture. Although the film remained intact, rusting progressed throughout the test and considerably darkened the color of the paint.

=Panel No. 32--China Clay.= This pigment gave excellent service for eighteen months. Afterwards indications of corrosion were shown, and apparent breakdown of the film was indicated.

[Ill.u.s.tration: China Clay

Asbestine

Gypsum]

=Panel No. 33--Asbestine.= In the same condition as Panel No. 32.

[Ill.u.s.tration: Excellent Surface shown by American Vermilion after nearly Four Years' Exposure]

=Panel No. 34--American Vermilion.= This pigment has given perfect protection to the plates. The film is strong and elastic, and upon removal reveals the bright steel. No chalking, checking, discoloration, or other signs of paint failure are shown. It would appear that the inhibitive characteristics of this pigment are p.r.o.nounced, and it promises to give efficient service for several years more.

=Panel No. 36--Lead Chromate.= This panel is in generally fair condition, but slight checking is shown.

[Ill.u.s.tration: Perfect Condition of Plate Painted with Zinc Chromate; One Half Stripped. (_Negative cracked_)]

=Panel No. 39--Zinc Chromate.= This panel is in condition similar to Panel No. 34, presenting a perfect appearance, with decided maintenance of color, elasticity of film, and freedom from any bad characteristics.

It has proved to be one of the highest type rust inhibitive pigments.

=Panel No. 40--Zinc-and-Barium-Chromate.= Although the color of this pigment is not very pleasing, it has proved itself to be the equal of zinc chromate in its protective value.

=Panel No. 41--Chrome Green.= In excellent condition. Presents an appearance similar to Panels Nos. 34 and 39. Its surface is perfect and will doubtless give service for many years.

=Panel No. 44--Prussian Blue.= This panel stands forth as the most wonderful moisture-excluder in the whole test, its surface presenting an appearance similar to a varnished plate, even after three years'

exposure. Action between the pigment and the oil, resulting in the formation of iron linoleate, may account for this property.

=Panel No. 45--Prussian Blue.= In same condition as Panel No. 44.

=Panel No. 48--Ultramarine Blue.= Soon after this test was exposed, early vehicle decay and excessive chalking were observed. The admittance of moisture may have caused the formation of acid with the sulphur content of the pigment, which would account for the rapid corrosion which followed. It is of a p.r.o.nounced stimulative type. The effect of stimulative under-coatings is well shown on some special plates on the fence, which when received were not pickled before painting, but had upon their surfaces the ordinary coating of mill scale. Over this had been stencilled in a triangular form the trade mark of the manufacturer.

The stencilling material was made of ultramarine blue. When these plates were painted with some of the special paints, and exposed, the stimulative nature of the ultramarine blue began to a.s.sert itself, and within a short time, wherever the stencil marks were located, signs of rust began to appear through the coatings of top paint which had been applied. Corrosion under these stencil marks became so great that the trade mark was plainly outlined in letters of rust. This would seem to be final proof that pigments of a stimulative nature should never be used for the priming of iron and steel.

=Panel No. 49--Zinc-Lead Chromate.= In excellent condition throughout, with a smooth surface and showing no corrosion. Stands in the same cla.s.s as Panels Nos. 34 and 39.

[Ill.u.s.tration: Effect of Stimulative Paint. Manufacturer's Trade Mark Stencilled on Bare Metal in Triangular Form, showing Through Subsequent Paint Coating]

=Panel No. 51--Black Magnetic Oxide of Iron.= In excellent condition.

CHAPTER XVII

THE SANITARY VALUE OF WALL PAINTS

=Decoration and Sanitation.= The proper decoration of the interior of dwellings and public buildings has become of even greater importance than the protection and decoration of exteriors. There is, moreover, an increasing demand for harmonious effects and the production of more sanitary conditions than have prevailed in the past. Up until a few years ago a great variety of wall papers of more or less pleasing appearance were almost exclusively used for the decoration of walls in the interior of buildings, and their application was commonly considered the most effective means of wall decoration. There seems to be no question, however, that the use of wall paper is steadily decreasing, and that the art of interior decoration is undergoing a transition to the almost universal use of paint.

Modern progress demands the maintenance of sanitary conditions for the benefit of the public welfare, and there is no doubt that from the standpoint of sanitation and hygiene, properly painted wall surfaces are far superior to papered walls. There is an abundance of evidence which shows that dust germs may easily be harbored, and thus disease transmitted from wall paper. In the tenement houses, which are common to the larger cities, and to a lesser extent in the dwellings found in smaller communities, where tenants are more or less transient, the continued maintenance of sanitary conditions presents a difficult problem. Infectious and epidemic illnesses generally leave behind bacilli of different types, which may find a culture medium in the fibrous and porous surfaces presented by wall paper, backed up as they invariably must be by starch, casein, or other organic pastes.

Occasionally the restrictions of local boards of health provide in such events for proper fumigation, but too often no precautions are taken to destroy the disease germs which are caught in the dust which collects on wall paper. As a rule, both tenant and landlord are oblivious to all conditions which cannot be readily seen or detected. Burning sulphur, one of the most effective means of fumigation, will generally cause bleaching and consequent fading of the delicate colors used in printing the designs upon wall paper. Was.h.i.+ng of the paper with antiseptic solutions will destroy its adhesiveness to the plaster and often cause bulging and general destruction.

[Ill.u.s.tration: Heavy Colonies of Bacteria Developing in Agar Jelly Treated with Was.h.i.+ngs from Wall Paper

Practically no Development of Bacterial Colonies in Agar Jelly Treated with Was.h.i.+ngs from Sanitary Wall Paint]

=Hospital Practice.= In hospitals, where it is necessary to maintain sanitary conditions, the walls are invariably painted, and requirements should demand the use of paints which can be washed frequently, so that there will be no possibility of uncleanliness. Inquiry made of a prominent surgeon[41] connected with one of the large metropolitan hospitals substantiated the writer's findings regarding the greater sanitary value of wall paints, and brought forth the information that in hospitals under construction provision had been made for the finis.h.i.+ng of walls so that a hard, non-absorbent, and washable surface might be obtained. The same authority stated that the common practice, in apartments and tenements, of covering the old wall paper over with a layer of new each time a tenant moved in, should be condemned, and that from a hygienic standpoint the use of sanitary wall paints should be advocated in all dwellings as well as public buildings.

[41] Dr. F. F. Gwyer, Cornell Uni. Med. Col., New York City.

If such conditions are maintained in hospitals, where special attention is paid to sanitation, it would appear that similar precautions should be equally as necessary in public buildings and in dwellings--wherever, in fact, people congregate or live.

=Sanitary Wall Paints.= There have recently appeared in trade a number of wall paints composed of non-poisonous pigments ground in paint vehicles having valuable waterproofing and binding properties, and of a nature to produce the flat or semi-flat finish that has become so popular. Such paints produce a sanitary, waterproof surface, which permits of frequent was.h.i.+ng. By their use it is possible to secure a more permanent and a wider range of tints than can be obtained with wall paper, as they are produced in a myriad of shades, tints and solid colors, from which any desired combination may be selected. On the border or on the body of walls decorated with such paints, attractive stencil designs, which bring out in relief the color combinations, may be applied.

For the decoration of chambers and living rooms, delicate French grays, light buffs, cream tints and ivory whites may be used, while in the library and other rooms richer and more solid colors, such as greens, reds, and blues, may be harmoniously combined.

=Defects of Wall Paper.= It recently occurred to the writer to investigate the conditions which obtain in many apartment houses in the larger cities. Inspection of a number of such places, in which wall paper had been exclusively used on the walls, showed generally bad conditions; bulging of the surfaces, caused by dampness in the walls, which had loosened up the binder, as well as peeling and dropping of the paper from the ceilings, were frequently observed. In many cases a shabby appearance was shown, accompanied by an odor which suggested decomposition of the paste binder used on the paper. The writer was impressed with the fact that such conditions could easily be avoided by the very simple expedient of using properly manufactured wall paints, which are so easily made dustproof and waterproof.

Samples of wall paper, which had been applied to plastered walls for a year or more, were obtained, and examination under the microscope showed a most uncleanly surface. Cultures were made of these samples, and bacilli of different types were developed in the culture medium in a short time.

=Experimental Evidence.= That the above conditions could not have existed, had proper wall paints been used, seemed doubtless, and suggested a carefully conducted experiment to prove the relative sanitary values of wall paper and wall paints. A large sheet of fibre board, such as is occasionally used to replace plastered walls, was painted on one side with a high-grade wall paint, three-coat work. A similar sheet was papered on one side with a clean, new wall paper.

These test panels were placed where unsanitary conditions, such as dampness, foul odors, and a scarcity of air were present. After a short period of exposure, the panels were taken to the bacteriological laboratory and a small section of the painted surface, about two inches square, as well as a small section of the papered surface of similar size, were removed and used for making cultures. In each case the surface of the section under test was washed with 100 c.c. of distilled, sterilized water. The was.h.i.+ngs which dripped from the surface were collected in a graduated flask. One c.c. of the was.h.i.+ngs was used in each case, admixed with bouillon and again with agar-agar. The enormous development of bacteria in the bouillon, treated with the was.h.i.+ngs from the wall-papered surface, was sufficient evidence to convince one of the greater sanitary value of the wall paint, the was.h.i.+ngs from which gave a culture practically free from bacteria. The colonies of bacteria shown in the petri-dish test made of the was.h.i.+ngs from wall paper further supports these findings. It will be noticed that the tests made from the was.h.i.+ngs of the wall paint show practical absence of bacteria, and was clear, as was the bouillon-solution test of the paint. The was.h.i.+ngs from the wall paper showed active development of bacteria, both in the bouillon and agar tests.

[Ill.u.s.tration: DEVELOPMENT OF BACTERIA IN BOUILLON SOLUTIONS

Note Practical Freedom of Bacteria in Clear Bouillon Solution Treated with Was.h.i.+ngs from Sanitary Wall Paint

Note Milky Appearance of Solution Due to Heavy Development of Bacteria in Bouillon Treated with Was.h.i.+ngs from Wall Paper]

_From the Conservation Standpoint_: It would be of interest to sum up in figures the acreage and cordage of wood that annually is transformed into pulp for the manufacture of wall paper. Unfortunately, there are no available statistics on this subject. It is clear, however, that from the standpoint of conservation the use of wall paints should take precedence over the use of wall paper.